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High temperature electrical conductivity in ZnSe:In and in CdSe:In under selenium vapor pressure

Identifieur interne : 000249 ( Russie/Analysis ); précédent : 000248; suivant : 000250

High temperature electrical conductivity in ZnSe:In and in CdSe:In under selenium vapor pressure

Auteurs : RBID : Pascal:07-0240774

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Abstract

High temperature electrical conductivity (HTEC) isotherms and isobars of ZnSe: In and of CdSe: In are compared. There are differencies in In-doping mechanisms of II-VI compounds. When HTEC isotherms and isobars of ZnSe: In and of CdSe: In, measured under metal component vapour pressure give both n-type conductivity then differences appear in the results of measurements under the selenium vapor pressure (pSe2). ZnSe: In isotherms in the last case are characterized by the conductivity type conversion but no such drastic change of HTEC type is observed on CdSe: In isotherms. Under the conditions of pSe2, the activation energy of HTEC isobars for ZnSe: In is ΔE ≃ 1.3 -1.6 eV and for CdSe: In is ΔE ≃ 1.2 eV. The onefold ionized substitutional In at Zn place is proposed to be compensated by native defects in ZnS: In and in CdSe: In under high pSe2. This native defect may be onefold ionized zinc vacancy for ZnSe: In and twofold ionized cadmium vacancy for CdSe: In. Association of defects occur at lower temperatures.

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Pascal:07-0240774

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<term>Activation energy</term>
<term>Cadmium selenides</term>
<term>Defect formation</term>
<term>Defects</term>
<term>Doping</term>
<term>Electrical conductivity</term>
<term>High temperature</term>
<term>II-VI semiconductors</term>
<term>Impurities</term>
<term>Impurity ionization</term>
<term>Indium additions</term>
<term>Inorganic compounds</term>
<term>N type conductivity</term>
<term>Transition element compounds</term>
<term>Vacancies</term>
<term>Vapor pressure</term>
<term>Zinc selenides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Haute température</term>
<term>Conductivité électrique</term>
<term>Pression vapeur</term>
<term>Dopage</term>
<term>Conductivité type n</term>
<term>Energie activation</term>
<term>Formation défaut</term>
<term>Lacune</term>
<term>Défaut</term>
<term>Impureté</term>
<term>Addition indium</term>
<term>Ionisation impureté</term>
<term>Zinc séléniure</term>
<term>Cadmium séléniure</term>
<term>Semiconducteur II-VI</term>
<term>Composé minéral</term>
<term>Métal transition composé</term>
<term>ZnSe</term>
<term>CdSe</term>
<term>7220F</term>
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<div type="abstract" xml:lang="en">High temperature electrical conductivity (HTEC) isotherms and isobars of ZnSe: In and of CdSe: In are compared. There are differencies in In-doping mechanisms of II-VI compounds. When HTEC isotherms and isobars of ZnSe: In and of CdSe: In, measured under metal component vapour pressure give both n-type conductivity then differences appear in the results of measurements under the selenium vapor pressure (p
<sub>Se2</sub>
). ZnSe: In isotherms in the last case are characterized by the conductivity type conversion but no such drastic change of HTEC type is observed on CdSe: In isotherms. Under the conditions of p
<sub>Se2</sub>
, the activation energy of HTEC isobars for ZnSe: In is ΔE ≃ 1.3 -1.6 eV and for CdSe: In is ΔE ≃ 1.2 eV. The onefold ionized substitutional In at Zn place is proposed to be compensated by native defects in ZnS: In and in CdSe: In under high p
<sub>Se2</sub>
. This native defect may be onefold ionized zinc vacancy for ZnSe: In and twofold ionized cadmium vacancy for CdSe: In. Association of defects occur at lower temperatures.</div>
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<sub>Se2</sub>
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<sub>Se2</sub>
, the activation energy of HTEC isobars for ZnSe: In is ΔE ≃ 1.3 -1.6 eV and for CdSe: In is ΔE ≃ 1.2 eV. The onefold ionized substitutional In at Zn place is proposed to be compensated by native defects in ZnS: In and in CdSe: In under high p
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</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Conductividad tipo n</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Energie activation</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Activation energy</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Formation défaut</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Defect formation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Formación defecto</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Lacune</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Vacancies</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Défaut</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Defects</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Impureté</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Impurities</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Addition indium</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Indium additions</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Ionisation impureté</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Impurity ionization</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Ionización impureza</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Zinc séléniure</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Zinc selenides</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Cadmium séléniure</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Cadmium selenides</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Semiconducteur II-VI</s0>
<s5>48</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>II-VI semiconductors</s0>
<s5>48</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>49</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>49</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>50</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>50</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>ZnSe</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>CdSe</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>7220F</s0>
<s4>INC</s4>
<s5>60</s5>
</fC03>
<fN21>
<s1>162</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>2006 E-MRS Fall Meeting, Symposium F</s1>
<s3>Warsaw POL</s3>
<s4>2006-09-04</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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